A radical mechanism of the reaction of molybdenum carbonyl complexes with bis(triethylgermyl)mercury |
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| Authors: | M I Sykhrannova A N Tatarnikov S Ya Khorshev E N Gladyshev |
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| Institution: | (1) Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600 Nizhnii Novgorod, Russian Federation |
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| Abstract: | The reaction of Cp(CO)3Mo]2 with (Et3Ge)2Hg occurs in toluene and THF by a radical mechanism. The interaction between Cp(CO)3Mo]2Hg and (Et3Ge)2Hg has a radical character only in THF. The formation of Cp(CO)3MoH at the first stage of these reactions substantially affects the further course of the process.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1648–1650, September, 1993. |
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| Keywords: | molybdenum complex reaction mechanism |
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