| 聚离子液体固载金纳米粒子的制备及其催化性能 |
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| 引用本文： | 彭建兵.聚离子液体固载金纳米粒子的制备及其催化性能[J].分子催化,2010,24(6). |
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| 作者姓名： | 彭建兵 |
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| 作者单位： | 1. 顺德职业技术学院,广东,顺德,528300
2. 湖南师范大学,精细催化合成研究所,湖南,长沙410081 |
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| 基金项目： | 国家自然科学基金(20803021) |
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| 摘 要： | 合成了氨基功能化乙烯基咪唑离子液体(AIL),利用氨基固定金纳米粒子以及双键的聚合作用,获得了聚离子液体固载金纳米粒子的催化剂(GNPs-P-AIL).采用红外光谱、紫外-可见光谱和透射电子显微镜等方法对GNPs-P-AIL进行了表征.结果表明,AIL在固定金纳米粒子并聚合后仍然保持着离子液体的基本结构,金纳米粒子分布均匀,粒径为6～8 nm.GNPs-P-AIL催化剂对苯乙烯环氧化具有较好的催化活性,以双氧水为氧化剂,在60℃下反应6 h时,苯乙烯的转化率和环氧苯乙烷的选择性分别可达81.5%和88.3%.
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| 关 键 词： | 氨基功能化离子液体 金纳米粒子 聚合 苯乙烯 环氧化 |
| 收稿时间： | 2010/9/16 0:00:00 |
| 修稿时间： | 2010/10/20 0:00:00 |
Preparation and Catalytic Performance of Gold Nanoparticles Stabilized by Ionic Copolymer |
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| PENG Jian-bin,DING Yan,TAN Rong,YIN Dong-hong,YU Ning-ya.Preparation and Catalytic Performance of Gold Nanoparticles Stabilized by Ionic Copolymer[J].Journal of Molecular Catalysis (China),2010,24(6). |
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| Authors: | PENG Jian-bin DING Yan TAN Rong YIN Dong-hong YU Ning-ya |
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| Institution: | PENG Jian-bin1,DING Yan2,TAN Rong2,YIN Dong-hong2,YU Ning-ya2(1.Shunde Polytechnic,Shunde 528300,China,2.Insititute of Fine Catalysis and Synthesis,Hunan Normal University,Changsha 410081,China) |
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| Abstract: | An amino-functionalized ionic liquid of N-(3-aminopropyl),N(3)-(vinyl)-imidazolium bromide(AIL) was synthesized and used to stabilize gold nanoparticles(GNPs).Further polymerization of the resultant GNP-containing AIL led to a composite catalyst(GNPs-P-AIL) in which GNPs were supported by ionic copolymer.The composite catalyst was characterized by means of Fourier transform infrared spectroscopy,ultraviolet-visible spectroscopy,and transmission electron microscopy.It was found that the structure of ionic li... |
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| Keywords: | Amino-functionalized ionic liquid Gold nanoparticles Polymerization Styrene Epoxidation |
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