| 固体碱在二氧化碳-甲醇法合成碳酸二甲酯反应中的作用 |
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| 引用本文： | 何永刚,淳远,朱建华,须沁华.固体碱在二氧化碳-甲醇法合成碳酸二甲酯反应中的作用[J].无机化学学报,2000,16(3):477-484. |
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| 作者姓名： | 何永刚 淳远 朱建华 须沁华 |
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| 作者单位： | 南京大学化学化工学院, 南京 210093,南京大学化学化工学院, 南京 210093,南京大学化学化工学院, 南京 210093,南京大学化学化工学院, 南京 210093 |
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| 基金项目： | 国家自然科学基金(No．29773020) |
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| 摘 要： | 本文探讨了固体碱的制备和预处理等因素对于CO2-甲醇法合成碳酸二甲酯(DMC)的影响,发现微波法所制碱性沸石等多孔材料的反应活性高于浸渍法所制样品。本文首次报道了微波辐射低压合成DMC的新方法,该法能极大地缩短反应时间并提高产物选择性。研究表明:CO2和甲醇生成DMC的反应在热力学上是几乎不能进行的,加入固体碱的实质是提供了一条耦合的途径。
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| 关 键 词： | 碳酸二甲酯 固体碱 二氧化碳一甲醇法 合成 |
| 收稿时间： | 1999/9/30 0:00:00 |
| 修稿时间： | 1999/12/30 0:00:00 |
The Role of Solid Base Played in Direct Synthesis of Dimethyl Carbonate from CO2 and Methanol |
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| HE Yong-Gang,CHUN Yuan,ZHU Jian-Hua and XU Qin-Hua.The Role of Solid Base Played in Direct Synthesis of Dimethyl Carbonate from CO2 and Methanol[J].Chinese Journal of Inorganic Chemistry,2000,16(3):477-484. |
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| Authors: | HE Yong-Gang CHUN Yuan ZHU Jian-Hua and XU Qin-Hua |
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| Institution: | Chemistry and Chemical Engineering College, Nanjing University, Nanjing 210093,Chemistry and Chemical Engineering College, Nanjing University, Nanjing 210093,Chemistry and Chemical Engineering College, Nanjing University, Nanjing 210093 and Chemistry and Chemical Engineering College, Nanjing University, Nanjing 210093 |
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| Abstract: | Microwave irradiation and impregnation were employed to prepare basic zeolites and other porous materials, and the activities of these samples were examined in the direct synthesis of dimethyl carbonate (DMC) from CO2 and methanol.The samples prepared by microwave irradiation exhibited a higher activity than those did by impregnation.Direct synthesis of DMC in the microwave field was first reported.This method shortened the reaction time effectively and brought a high CH3OCH3 for this reaction since there was almost no by-product CH3OCH3 formed.Finally the mechanism of this synthesis was also explored in the terms of thermodynamics.According to thermodynamically analysis this reaction could hardly proceed.The purpose of adding solid base was to provide a coupling way instead of a catalyst. |
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| Keywords: | dimethyl carbonate solid base CO2 microwave basic zeolites |
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