Palladium(ii) catalyzed thiono-thiolo rearrangement of propargyl thionophosphates |
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Affiliation: | 1. University College, M G Road, Palayam, Thiruvananthapuram 695 034, Kerala, India;2. Soild State Physics Division, Bhabha Atomic Research Centre, Mumbai, 40005, India;3. Christian College, Kattakada, Thiruvananthapuram 695 572, Kerala, India;4. Government College For Women, Vazhuthacaud, TVM 695014, Kerala, India;1. Department of Chemical and Biological Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Republic of Korea;2. Department of Chemical Engineering, Kumoh National Institute of Technology, 61 Daehak-ro, Gumi, Gyeongbuk 39177, Republic of Korea |
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Abstract: | Palladium(II) effectively catalyzes the [3,3]-sigmatropic type rearrangement of propargyl thionophosphates to provide allenyl thiolophosphates specifically. |
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