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Classical light scattering studies on structure formation in polymer solutions
Authors:Ulrich Gohlke  Gudrun Rother  Andreas Otto  Juergen Hartmann
Abstract:The scattered light is very sensitive to the presence of supermolecular structures in polymer solutions, offering the possibility to study structure formation in situ by classical light scattering and to characterize the generated particles. An improved analysis of light scattering data yields information on the structure type, polydispersity of the systems, particle mass and size as well as the degree of swelling. The flocculation process of ampholytic modified poly(acrylonitrile) was investigated in dependence on the pH-value and the content of different salts in the solvent. Results obtained give a deeper insight into the flocculation mechanism.
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