| 逐级电子转移过程的0.5次微分电分析法 |
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| 引用本文： | 薛永军,袁倬斌. 逐级电子转移过程的0.5次微分电分析法[J]. 化学学报, 1989, 47(12): 1201-1205 |
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| 作者姓名： | 薛永军 袁倬斌 |
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| 作者单位： | 中国科学技术大学研究生院 |
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| 基金项目： | 国家自然科学基金，中国科学院基金 |
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| 摘 要： | 卷积伏安法(新极谱法)是近十年发展起来的一种新电化学分析方法, 本文报导了逐级电子转移过程的0.51次微分电分析法的理论和实验结果, 用计算机模拟了理论极谱图, 讨论了标准分离电位和电子转移数对极谱的影响 。并选择0.1M的NH~4Cl-NH~4OH作为缓冲溶液中铜(II)的还原作为检验理论和实验之间的关系。
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| 关 键 词： | 伏安法 极谱分析 电子传递 电化学分析 卷积 |
Half-differential polarography with multistep reversible charge transfers |
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| XUE YONGJUN,YUAN ZHUOBIN. Half-differential polarography with multistep reversible charge transfers[J]. Acta Chimica Sinica, 1989, 47(12): 1201-1205 |
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| Authors: | XUE YONGJUN YUAN ZHUOBIN |
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| Abstract: | The theory of 0.5th order differential polarog. for multistep reversible charge transfers is proposed, and a theor. polarogram was computer simulated. The effect of both the standard potential separation (DE? and the no. of electrons on polarograms is discussed. The reduction of Cu(II) in 0.10M NH4Cl-NH4OH was selected to test the theory, and reasonable agreement between theory and experiment was obtained. |
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| Keywords: | VOLTAMMETRY POLAROGRAPHIC ANALYSIS ELECTRON TRANSFER ELECTROCHEMICAL ANALYSIS CONVOLUTION |
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