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Thermodynamic Properties of N-(Trimethylsily)ethyleneimine N-(Triethylsily)ethyleneimine and (Dimethylphenylsilyl)ethyleneimine Complexes with Zinc Chloride in the Range 0-340 K
Authors:Kulagina  T G  Lebedev  B V  Kochetkov  A M
Institution:(1) Chemistry Research Institute, Lobachevskii Nizhegorodskii State University, Nizhny Novgorod, Russia
Abstract:Tmperature dependence of heat capacity of N-(trimethylsilyl)ethyleneimine, N-(triethylsilyl)-ethyleneimine, N-(dimethylphenylsilyl)ethyleneimine with zinc chloride was studied in the 5-340 K rangein an adiabatic vacuum calorimeter with sim0.2% error. From the data obtained tge complexes thermodynamicfunctions C0 p(T), H 0(T)-H 0(0), S 0(T)-S 0(0) and G 0(T)-H 0(0) are obtained in the 0-340 K, as well as fractal dimensions D and characteristic temperatures THgrmax for the functions of gractal heat capacity of solid substances.
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