Thermodynamic Properties of N-(Trimethylsily)ethyleneimine N-(Triethylsily)ethyleneimine and (Dimethylphenylsilyl)ethyleneimine Complexes with Zinc Chloride in the Range 0-340 K |
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Authors: | Kulagina T G Lebedev B V Kochetkov A M |
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Institution: | (1) Chemistry Research Institute, Lobachevskii Nizhegorodskii State University, Nizhny Novgorod, Russia |
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Abstract: | Tmperature dependence of heat capacity of N-(trimethylsilyl)ethyleneimine, N-(triethylsilyl)-ethyleneimine, N-(dimethylphenylsilyl)ethyleneimine with zinc chloride was studied in the 5-340 K rangein an adiabatic vacuum calorimeter with 0.2% error. From the data obtained tge complexes thermodynamicfunctions C0
p(T), H
0(T)-H
0(0), S
0(T)-S
0(0) and G
0(T)-H
0(0) are obtained in the 0-340 K, as well as fractal dimensions D and characteristic temperatures max for the functions of gractal heat capacity of solid substances. |
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Keywords: | |
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