| 苝醌/富勒烯C60超分子与电子给体的电子转移作用 |
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| 引用本文： | 高云燕,欧植泽,杨国强,王雪松,张智斌,礼嵩明.苝醌/富勒烯C60超分子与电子给体的电子转移作用[J].物理化学学报,2009,25(1):74-78. |
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| 作者姓名： | 高云燕 欧植泽 杨国强 王雪松 张智斌 礼嵩明 |
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| 作者单位： | Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, P. R. China; Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China; Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China |
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| 摘 要： | 利用紫外-可见吸收光谱、瞬态吸收光谱及X射线衍射等方法研究了苝醌染料竹红菌素镁离子配合物(Mg2+-HA)与富勒烯C60的相互作用. 结果表明, Mg2+-HA与C60在溶液和固体状态下都能够形成稳定的超分子. Mg2+-HA存在条件下, C60能够溶于多种极性溶剂, 在二甲基亚砜(DMSO)中的溶解度能够达到1×10-4 mol·L-1. 作为超分子体系中的光捕获分子, Mg2+-HA能显著地提高C60与N,N-二甲基苯胺(DMA)的光诱导电子转移反应效率, 生成的C60负离子自由基的电子自旋共振光谱(ESR)信号强度比未加入Mg2+-HA时增强了9倍左右.
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| 关 键 词： | 苝醌 富勒烯C60 光诱导电子转移反应 超分子 |
| 收稿时间： | 2008-08-01 |
| 修稿时间： | 2008-10-06 |
Photoinduced Electron Transfer between Perylenequinonoid/Fullerene C60 Supramolecule and Electron Donor |
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| GAO Yun-Yan,OU Zhi-Ze,YANG Guo-Qiang,WANG Xue-Song,ZHANG Zhi-Bin,LI Song-Ming.Photoinduced Electron Transfer between Perylenequinonoid/Fullerene C60 Supramolecule and Electron Donor[J].Acta Physico-Chimica Sinica,2009,25(1):74-78. |
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| Authors: | GAO Yun-Yan OU Zhi-Ze YANG Guo-Qiang WANG Xue-Song ZHANG Zhi-Bin LI Song-Ming |
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| Institution: | Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, P. R. China; Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China; Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China |
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| Abstract: | The magnesiumcomplex of hypocrellinA(Mg2+-HA) (a perylenequinonoid compound) and pristine fullerene C60 was used to construct supramolecular assemblies in solution and in the solid state. The assembly was characterized by UV-Vis, transient absorption spectroscopy, and powder X-ray diffraction (XRD). The solubility of C60 in polar solvent improves significantly in the presence of Mg2+-HA. The solubility of C60 in dimethyl sulfoxide (DMSO) is 1×10-4 mol·L-1 when C60 is allowed to complex with Mg2+-HA(4×10-4 mol·L-1). Acting as an antenna molecule in the supramolecular system, Mg2+-HA remarkably enhances the photoinduced electron transfer efficiency between C60 and an electron donor, N,N-dimethylaniline (DMA). The electron spin resonance (ESR) signal intensity of C6-0·increases 9-fold as strong as that in the absence of Mg2+-HA. |
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| Keywords: | Perylenequinonoid Fullerene C60 Photoinduced electron transfer Supramolecule |
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