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Study of the Structure of Lithium Thiocyanate Complexes with Benzo-15-Crown-5 by X-ray Diffraction and IR Spectroscopy
Authors:L G Kuz’mina  L I Demina  S V Demin  N A Shokurova  V I Zhilov  A Yu Tsivadze
Institution:1.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia;2.Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences,Moscow,Russia
Abstract:The complex formation of lithium thiocyanate with benzo-15-crown-5 (B15C5) was studied. The possibility of formation of both anhydrous and crystal water-containing complexes was demonstrated. The complexes LiB15C5NCS and LiB15C5H2ONCS were synthesized and characterized by X-ray diffraction and IR spectroscopy.
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