The Fluorescent Properties and Electronic Structure of Nd(111) Complexes with Carboxylic Acids |
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Authors: | I V Kalinovskaya Yu M Nikolenko |
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Institution: | 1.Institute of Chemistry, Far East Branch,Russian Academy of Sciences,Vladivostok,Russia |
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Abstract: | Mixed-ligand neodymium(III) complexes with carboxylic acids and nitrogen- and phosphorus-containing neutral ligands, which luminesce in the near-IR region, are studied by luminescence and X-ray photoelectron spectroscopies. It is found that coordination of neutral ligands through the nitrogen donor atom leads to an increase in the electron density at the neodymium(III) ion. |
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