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Non ideality of free diffusion boundaries
Authors:L. Ambrosone  V. Vitagliano  C. Della Volpe  R. Sartorio
Affiliation:(1) Facoltà di Agraria, Università del Molise, Campobasso;(2) Dipartimento di Chimica, Università Federico II, Napoli 4, Via Mezzocannone, 80134 Naples, Italy
Abstract:The evolution of free diffusion boundaries with various initial perturbations is described and compared with a set of experimental data for the system KCl-Water. The necessity of extrapolating to infinite time of not only the experimental diffusion coefficient (as a function of 1/t'), but also the experimental Q quantily (as a function of 1/t'2) is stressed.
Keywords:Diffusion  Gouy technique
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