Theoretical phase diagrams for [N(CD3)4]2ZnCl4 crystal |
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Authors: | D. G. Sannikov |
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Affiliation: | 1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia
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Abstract: | A theoretical phase diagram of [N(CD3)4]2ZnCl4 crystal is constructed in the plane of two thermodynamic-potential coefficients. The orientation of the temperature (T) and pressure (P) axes is chosen in the diagram. The first diagram is used as a basis to construct the second theoretical T-P phase diagram, expanded to the region of weak negative pressures for nondeuterated [N(CH3)4]2ZnCl4 crystal. It is suggested that this region can be observed for deuterated [N(CD3)4]2ZnCl4 crystal. |
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