Thermochromic triangular [MCo2] (M = Rh, Ir, Ru) clusters containing a planar metalladithiolene ring in eta3 coordination |
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| Authors: | Nakagawa Norikiyo Yamada Teppei Murata Masaki Sugimoto Manabu Nishihara Hiroshi |
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| Institution: | Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Japan. |
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| Abstract: | The first series of triangular cluster complexes of MCo(2)] (M = Rh, Ir, Ru) with a planar metalladithiolene ring coordinating in the eta(3)-bonding mode were synthesized, and the crystal structures, spectral and electrochemical properties, and thermochromism of these complexes were revealed. |
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