A Nanosized Gly‐Decorated Praseodymium‐Stabilized Selenotungstate Cluster: Synthesis,Structure, and Oxidation Catalysis |
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| Abstract: | A flexible one‐pot strategy with pyramidal SeIV heteroatoms was employed for the assembly of the praseodymium‐containing gly‐decorated polyoxotungstate [{Pr3(H2O)10[Se2W22O76(gly)2]}2(Se2W7O30H2)]18− ( 1 a ), which is constructed from one {Se2W7O30H2} unit and two identical {Pr3(H2O)10[Se2W22O76(gly)2]} units. Furthermore, the catalytic performance of Cs2Na4H12[{Pr3(H2O)10[Se2W22O76(gly)2]}2(Se2W7O30H2)] ⋅ 25 H2O ( 1 ) for alkene epoxidation with hydrogen peroxide was investigated under mild reaction conditions, and the experimental results suggested that compound 1 exhibits good catalytic performance for the epoxidation of cyclooctene. |
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| Keywords: | cyclooctene epoxidation heteroatoms peroxides polyoxometalates |
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