Study of Six Green Insensitive High Energetic Coordination Polymers Based on Alkali/Alkali‐Earth Metals and 4,5‐Bis(tetrazol‐5‐yl)‐2 H‐1,2,3‐triazole

Constructing insensitive high‐performance energetic coordination polymers (ECPs) with alkali/alkali‐earth metal ions and a nitrogen‐rich organic backbone has been proved to be a feasible strategy in this work. Six diverse dimensional novel ECPs (compounds 1 – 6 ) were successfully synthesized from Na^I, Cs^I, Ca^II, Sr^II, Ba^II ions and a nitrogen‐rich triheterocyclic 4,5‐bis(tetrazol‐5‐yl)‐2 H ‐1,2,3‐triazole (H₃BTT). All compounds show outstanding stability and low sensitivity, the thermal stability of these ECPs are significantly improved as the structural reinforcement increases from 1D to 3D, in which the decomposition temperature of 3D Ba^II based compound 6 is as high as 397 °C. Long‐term storage experiments show that compounds 5 and 6 are stable enough at high temperature. Moreover, the six compounds hold considerable detonation performances, in which Ca^II based compound 5 possesses the detonation velocity of 9.12 km s⁻¹, along with the detonation pressure of 34.51 GPa, exceeding those of most energetic coordination polymers. Burn tests further certify that the six compounds can be versatile pyrotechnics.