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Importance of Inherent Substrate Reactivity in Enzyme‐Promoted Carbocation Cyclization/Rearrangements
Abstract:The importance of inherent substrate reactivity for terpene synthase enzymes is discussed, with a focus on recent experimental tests of predictions derived from computations on gas‐phase reactivity of carbocations.
Keywords:carbocations  enzymes  inherent reactivity  intrinsic reactivity  terpenes
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