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Importance of Inherent Substrate Reactivity in Enzyme‐Promoted Carbocation Cyclization/Rearrangements |
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| Abstract: | The importance of inherent substrate reactivity for terpene synthase enzymes is discussed, with a focus on recent experimental tests of predictions derived from computations on gas‐phase reactivity of carbocations. |
| Keywords: | carbocations enzymes inherent reactivity intrinsic reactivity terpenes |