A Magneto‐optical Molecular Device: Interplay of Spin Crossover,Luminescence, Photomagnetism,and Photochromism |
| |
Abstract: | A bis(pyrazolylpyridyl) ligand, L, containing a central photochromic dithienylethene spacer predictably forms a ferrous Fe2L3]4+ helicate exhibiting spin crossover (SCO). In solution, the compound Fe2L3](ClO4)4 ( 1 ) preserves the magnetic properties and is fluorescent. The structure of 1 is photo‐switchable following the reversible ring closure/opening of the central dithienylethene via irradiation with UV/visible light. This photoisomerization switches on and off some emission bands of 1 and provides a means of externally manipulating the magnetic properties of the assembly. |
| |
Keywords: | Dithienylethen Fluoreszenz Molekulare Baueinheiten Photoschaltung Spin-Crossover |
|
|