| Abstract: | A dinuclear ruthenium complex [RuII(NCNHC O)(pic)2]22+ ( 2 ) was firstly prepared and characterized spectroscopically and electrochemically. Instead of the conventional ligand exchange, complex 2 dissociates in situ to afford two single‐site Ru aqua complexes, [RuII(OH2)(NCNHC O)(pic)2]+, which mediates water oxidation through proton‐coupled electron transfer events. In electrokinetic studies, complex 2 demonstrated a TOF of 150.3 s−1 comparable to those state‐of‐the‐art catalysts at neutral conditions. TONs of 2173 and 217 were attained in chemical and photochemical water oxidation when 2 was used as a catalyst, exhibiting good stability. Notably, a TOF of 1.3 s−1 was achieved at CAN‐driven water oxidation, which outperformed most of the reported single‐site Ru complexes, indicating that complex 2 is one of most active water oxidation catalysts (WOCs) to date. The unique coordination configuration and outstanding catalytic performance of complex 2 might shed light on the design of novel molecular WOCs. |
