| 橘红色发光的八羟基喹啉锌和1,4-二乙烯基苯的交替共聚物 |
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| 引用本文： | 梁福顺,王广,马东阁,苏光平,王利祥,景遐斌,王佛松.橘红色发光的八羟基喹啉锌和1,4-二乙烯基苯的交替共聚物[J].发光学报,2002,23(1):12-16. |
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| 作者姓名： | 梁福顺 王广 马东阁 苏光平 王利祥 景遐斌 王佛松 |
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| 作者单位： | 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室, 吉林长春, 130022 |
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| 基金项目： | 国家自然科学基金，29725410,29992530， |
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| 摘 要： | 经由配位聚合反应,合成了八羟基喹啉锌和1,4二乙烯基苯的交替共聚物.所合成的聚合物通过元素分析和红外光谱进行了表征.在365nm的紫外光照射下,聚合物呈现强的橘红色发光,在乙氰溶液中的最大发光峰位在571nm.热失重分析表明,这种含Znq2的聚合物具有稳定的热力学性质,热失重5%的温度大于439℃.这种聚合物的电致发光性质正在研究中.
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| 关 键 词： | 合成 金属配位聚合物 橘红色发光 |
A Novel Orange-red Light Emitting Metal-complex Polymer: Copolymer of Bis(8-hydroxyquinoline)zinc and 1,4-Divinylene Phenylene |
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| Abstract.A Novel Orange-red Light Emitting Metal-complex Polymer: Copolymer of Bis(8-hydroxyquinoline)zinc and 1,4-Divinylene Phenylene[J].Chinese Journal of Luminescence,2002,23(1):12-16. |
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| Authors: | Abstract |
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| Institution: | The State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun |
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| Abstract: | The synthesis, by co-ordination reaction, of a novel stable bis(8-hydroxyquinoline) zinc (Znq2)-containing metal complex polymer (copolymerization of Znq2 and 1, 4-divinylene phenylene) is reported. The resulting polymer, which is characterized by EA and IR, shows strong orange-red emission (λem = 571nm in solution). As determinded by TG analysis, the Znq2 containing polymer is thermally stable with a 5% weight-loss temperature higher than 439℃ under nitrogen. |
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| Keywords: | synthesis metal-complex polymer orange-red light emission |
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