TfOH-catalyzed allylation of alkynes with cyclic Baylis-Hillman alcohols |
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Authors: | Chen Wu Dong Wang |
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Affiliation: | Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China |
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Abstract: | The substitution reaction of cyclic Baylis-Hillman alcohols with arylacetylenes was achieved under the catalysis of TfOH in nitromethane. The γ,δ-unsaturated ketones were obtained in moderate to good yields. |
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Keywords: | Baylis-Hillman alcohols Alkynes TfOH Ketones Allylation |
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