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TfOH-catalyzed allylation of alkynes with cyclic Baylis-Hillman alcohols
Authors:Chen Wu  Dong Wang
Affiliation:Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Abstract:The substitution reaction of cyclic Baylis-Hillman alcohols with arylacetylenes was achieved under the catalysis of TfOH in nitromethane. The γ,δ-unsaturated ketones were obtained in moderate to good yields.
Keywords:Baylis-Hillman alcohols   Alkynes   TfOH   Ketones   Allylation
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