Enantioselective synthesis of polyketide segments through vinylogous Mukaiyama aldol reactions |
| |
| Authors: | Serkan Simsek |
| |
| Institution: | Institut für Organische Chemie, Leibniz Universität Hannover, Schneiderberg 1b, 30167 Hannover, Germany |
| |
| Abstract: | The synthesis of polyketide segments through the vinylogous Mukaiyama aldol reaction is reported. The use of chiral oxazaborolidines allows using terminal substituted ketene acetals and provides access to extended segments and two new chiral centers. |
| |
| Keywords: | Vinylogous Mukaiyama aldol Polyketides Oxazaborolidines Natural products Enantioselective |
| 本文献已被 ScienceDirect 等数据库收录！ |
