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Preparation of alkyl-containing derivatives of chitosan and its oligomers in polymer-analogous reactions
Authors:E N Fedoseeva  A V Budruev  L A Smirnova  Yu D Semchikov  V B Fedoseev
Institution:(1) Nizhni Novgorod State University, pr. Gagarina 23/2, Nizhni Novgorod, 603950, Russia;(2) Blagonravov Institute of Engineering Science, (Nizhni Novgorod Branch), Russian Academy of Sciences, ul. Belinskogo 85, Nizhni Novgorod, 603024, Russia
Abstract:It has been shown that the interaction of chitosan and oligochitosan with unsaturated acrylic esters via the nucleophilic addition mechanism and their condensation with heptadecyl isocyanate yield hydrophobic alkyl-containing derivatives of the above polymers. The method of modification of oligochitosan in reactions via end functional groups is developed.
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