Levelcrossing Experimente im Tm I-Spektrum

A semi phenomenological dynamical theory for the rotations of the BO₆ octahedra in ABO₃ perovskites is proposed, which accounts for the soft mode and the central peak forT≧T _c observed by neutron scattering in SrTiO₃. The neutron scattering cross section is discussed. The EPR line width is predicted to diverge as ?^?ν(1–2η) and as ?^?ν(2–2η) for three- and two dimensional correlations with ?=(T-T _c )/T _c . The theory is generalized to other structural transitions.