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Graphene oxide assisted facile hydrothermal synthesis of LiMn0.6Fe0.4PO4 nanoparticles as cathode material for lithium ion battery
Authors:Changchang Xu Li Li Fangyuan Qiu Cuihua An Yanan Xu Ying Wang Yijing Wang Lifang Jiao Huatang Yuan
Institution:Institute of New Energy Material Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Key Laboratory of Advanced Energy Materials Chemistry, Nankai University, Tianjin 300071, China
Abstract:Assisted by graphene oxide(GO),nano-sized LiMn_(0.6)Fe_(0.4)PO_4 with excellent electrochemical performance was prepared by a facile hydrothermal method as cathode material for lithium ion battery.SEM and TEM images indicate that the particle size of LiMn_(0.6)Fe_(0.4)PO_4(S2)was about 80 nm in diameter.The discharge capacity of LiMn_(0.6)Fe_(0.4)PO_4 nanoparticles was 140.3 mAh-g^1 in the first cycle.It showed that graphene oxide was able to restrict the growth of LiMn_(0.6)Fe_(0.4)PO_4 and it in situ reduction of GO could improve the electrical conductivity of LiMn_(0.6)Fe_(0.4)PO_4 material.
Keywords:hydrothermal method  cathode material  lithium-ion batteries  graphene oxide  nano-particles
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