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Synthesis and mesomorphic properties of 4-n-alkoxy 4'-[4-((4-n-alkoxy-2,3,5,6-tetrafluoro-phenyl)ethynyl)benzyloxy]benzoates
Authors:Jianxun Wen  Huiyong Yin  Minquan Tian  Qi Chen
Institution:  a Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China
Abstract:Two series of tolane-based liquid crystals have been prepared that incorporate a tetrafluorophenyl moiety and a flexible methyl ether bond into the core structure. The mesomorphic properties have been studied by polarizing microscopic textural observation and DSC measurements. By comparison with their non-fluorinated analogues, the effect of tetrafluorophenylene on mesomorphic behaviour has been discussed in this paper.
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