A study of the parameterisation of the uniaxial model of superparamagnetic relaxation

Mössbauer spectra of the iron storage protein ferritin taken over a range of temperatures exhibit the characteristic behaviour of superparamagnetic relaxation, and can be used to investigate a model for the superparamagnetic relaxation of a sample of small magnetic particles. A computer program is used to calculate a series of Mössbauer spectra based on the relaxation model, and these theoretical spectra are then fitted simultaneously to all the variable temperature experimental spectra, with the parameters of the uniaxial anisotropy model as the only variables.