Kinetics of aquation of pentaammine(substituted salicylato)cobalt(III) complexes by ferric ion |
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Authors: | Anadi C. Dash Rabindra K. Nanda Himansu K. Patnaik |
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Affiliation: | (1) Department of Chemistry, Utkal University, Bhubaneswar-4, India;(2) Department of Chemistry, B. J. B. College, Bhubaneswar-6, India |
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Abstract: | Summary The aquation of pentaammine (substituted salicylato) cobalt(III) complexes [(NH3)5CoO2CC6H3(X)OH]2+,X = 5-SO3, 5-Br, 5-NO2, and 3-NO2 in the presence of ferric ion was studied spectrophotometrically in the 65°–80° range. Ferric ion catalyses the aquation of the substratesvia formation of a reactive binuclear species.Reprints of this article are not available. |
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