Kinetics of aquation of pentaammine(substituted salicylato)cobalt(III) complexes by ferric ion期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Kinetics of aquation of pentaammine(substituted salicylato)cobalt(III) complexes by ferric ion

Authors:	Anadi C Dash Rabindra K Nanda Himansu K Patnaik

Institution:	(1) Department of Chemistry, Utkal University, Bhubaneswar-4, India;(2) Department of Chemistry, B. J. B. College, Bhubaneswar-6, India

Abstract:	Summary The aquation of pentaammine (substituted salicylato) cobalt(III) complexes (NH₃)₅CoO₂CC₆H₃(X)OH]²⁺,X = 5-SO₃, 5-Br, 5-NO₂, and 3-NO₂ in the presence of ferric ion was studied spectrophotometrically in the 65°–80° range. Ferric ion catalyses the aquation of the substratesvia formation of a reactive binuclear species.Reprints of this article are not available.

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