Calix[4]arene-functionalized naphthalene and perylene imide dyes |
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Authors: | Vysotsky Myroslav O Böhmer Volker Würthner Frank You Chang-Cheng Rissanen Kari |
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Affiliation: | Fachbereich Chemie und Pharmazie, Abteilung Lehramt Chemie, Johannes Gutenberg-Universit?t, Duesbergweg 10-14, D-55099 Mainz, Germany. |
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Abstract: | [reaction: see text] Calix[4]arenes bearing one, two, or four 1,8-naphthyl imide groups at the wide rim and bis-calix[4]arenes connected via perylene-bisimide dye spacers have been synthesized. The low-temperature NMR spectrum of the tetranaphthylimide suggests, in agreement with a crystal structure, a C2-symmetrical pinched cone conformation stabilized via face-to-face pi-pi interactions between opposite naphthylimide groups. UV-vis and fluorescence studies have been carried out for the perylene bis-calix[4]arene dyes. |
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