Tuning the reaction paths in palladium(0)-catalyzed coupling-cyclization reaction of beta-amino allenes with organic halides: a substituent switch |
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Authors: | Ma Shengming Gao Wenzhong |
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Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P. R. China. masm@pub.sioc.ac.cn |
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Abstract: | reaction: see text] Substituent effects on the allene moiety and the N-protecting group were found to be the dominant factor in determining the reaction paths in the Pd(0)-catalyzed coupling-cyclization reaction of beta-amino allenes with organic halides. |
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