Ruthenium-catalyzed hydrosilylation of 1-alkynes with novel regioselectivity |
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| Authors: | Kawanami Yukio Sonoda Yoshiya Mori Takashi Yamamoto Keiji |
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| Institution: | Department of Materials Science and Environmental Engineering, Tokyo University of Science, Yamaguchi, 1-1-1 Daigaku-Dori, Onoda 756-0884, Japan. yamamoto@ed.yama.tus.ac.jp |
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| Abstract: | reaction: see text] A ruthenium catalyst precursor bearing a bulky and electron-donating pentamethylcyclopentadienyl (Cp) ligand, typically CpRuH3(PPh3), mediates hydrosilylation of several 1-alkynes with novel regioselectivity to give preferentially 2-silyl-1-alkenes. |
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