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Micro-Raman studies on the conformational behaviors of monosodium glutamate in dehydration process
Authors:Jing Jing Shou  Guang Zeng  Hao Zhang  Yun Hong Zhang The Institute of Chemical Physics  Key Laboratory of Cluster Science  Beijing Institute of Technology  Beijing  China
Institution:The Institute of Chemical Physics, Key Laboratory of Cluster Science, Beijing Institute of Technology, Beijing 100081, China
Abstract:The conformational behaviors of monosodium glutamate(MSG) in a dehydration process were studied by Micro-Raman spectroscopy in combination with Hartree-Fock calculations using 6-31+G~* method.The dehydration process of the MSG droplet was performed by decreasing the ambient relative humidity(RH).The intensity ratio of the 935 cm~(-1) band to 884 cm~(-1) band(I_(935)/ I_(884)) kept decreasing when RH decreased.By optimizing the geometries with different fixed dihedral angles,the downtrend of(I_(935)/ I_(884)...
Keywords:Raman  MSG  Calculation  Dehydration  Intensity  Dihedral angle  
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