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原油中微量金属元素的测定及聚类分析
引用本文:陈发荣,杨春茹,李景喜,杨东方,郑立,王小如.原油中微量金属元素的测定及聚类分析[J].分析科学学报,2011,27(3):371-374.
作者姓名:陈发荣  杨春茹  李景喜  杨东方  郑立  王小如
作者单位:中国海洋大学化学化工学院;国家海洋局第一海洋研究所;上海海洋大学水产与生命学院;
基金项目:海洋公益性行业科研专项(No.200705011); 海洋溢油鉴别与损害评估技术重点实验室开放基金(No.200920); 海洋一所基本科研业务费专项(2007G17); 科技基础性工作专项(2008FY230600)
摘    要:采用电感耦合等离子体质谱(ICP-MS)法测定了国内外18种原油样品中V、Ni、Cu等13种微量金属元素的含量.结果显示,方法的线性关系良好,相关系数r≥0.9995,相对标准偏差(RSD)<5.0%,方法加标回收率为95.2%~116.2%.不同原油样品以Ni/V数值为聚类变量进行聚类分析,结果发现,国外与国内以及国...

关 键 词:原油  电感耦合等离子体质谱  微量金属元素  聚类分析

Determination of Trace Metal Elements and Cluster Analysis on Different Crude Oil
CHEN Fa-rong,YANG Chun-ru,LI Jing-xi,YANG Dong-fang,ZHENG Li,WANG Xiao-ru.Determination of Trace Metal Elements and Cluster Analysis on Different Crude Oil[J].Journal of Analytical Science,2011,27(3):371-374.
Authors:CHEN Fa-rong  YANG Chun-ru  LI Jing-xi  YANG Dong-fang  ZHENG Li  WANG Xiao-ru
Institution:CHEN Fa-rong*1,3,YANG Chun-ru2,LI Jing-xi3,YANG Dong-fang2,ZHENG Li3,WANG Xiao-ru1,3(1.College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266100,2.College of Fisheries and Life Science,Shanghai Ocean University,Shanghai 201306,3.First Institute Oceanography of State Oceanic Administration,Qingdao 266061)
Abstract:A method for the determination of V,Ni,Cu,etc.in different crude oil by inductively coupled plasma mass spectrometry was presented.The recoveries were in the range of 95.2%~116.2% with relative standard deviations less than 5.0%.The analysis results showed that the Ni/V ratio different in different crude oil from oversea and oil fields at Bohai sea and Nanhai sea.
Keywords:Crude oil  Inductively coupled plasma mass spectrometry  Trace metal elements  Cluster analysis  
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