| Iron-catalyzed ketonization of 2-aryl-1,1-dibromoalkenes with KOAc:Synthesis of α-acetoxy aryl ketones via a Michael-like addition process |
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| 作者姓名： | Ming Zhao Chun Xiang Kuang Xue Zhi Cheng Qing Yang |
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| 作者单位： | a Department of Chemistry, Tongji University, Shanghai 200092, China;b Department of Biochemistry, School of Life Sciences, Fudan University, Shanghai 200433, China |
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| 基金项目： | supported by Natural Science Foundation of China(No,30873153); the Key Projects of Shanghai in Biomedical(No.08431902700); the Scientific Research Foundation of State Education Ministry for the Returned Overseas Chinese Scholars |
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| 摘 要： | A novel and convenient iron-catalyzed ketonization of 2-aryl-1,1-dibromoalkenes with KOAc has been achieved.A series ofα-acetoxy aryl ketones were prepared with moderate yields via 2-carbon position functionalization of 2-aryl-1,1-dibromoalkenes.
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| 关 键 词： | Iron catalyst Ketonization Dibromoalkene α-Acetoxy ketone Potassium acetate |
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