A facile synthesis of novel optically active R,R-2-(4-(2-(4-(5-chloro-3-halo-pyridin-2-yloxy)-phenoxy)-propionyloxy)-phenoxy)-propionic acid esters using cyanuric chloride as potential herbicide |
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Authors: | Hassan Tajik Akbar Dadrasa Shokufeh Aghabeygib a |
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Institution: | a Department of Chemistry, Faculty of Sciences, University of Guilan, P.O.Box 41335-1914, Rasht, Iran;b Department of Chemistry, Islamic Azad University, East Tehran Branch, P.O.Box 33955-163, Qiamdasht, Iran |
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Abstract: | A facile method for the synthesis of a new series of R,R-2-(4-(2-(4-(5-chloro-3-halopyridin-2-yloxy)-phenoxy)-propionyloxy)-phenoxy) -propionic acid ester derivatives containing a halo-substituted pyridine carrying two R,R chiral centers from(R)-2-(4- hydroxyphenoxy)propionic acid,halopyridines and alcohols using base/cyanuric chloride/catalyst system is reported.Their herbicidal activities against grass weeds and crops selectivity were evaluated. |
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Keywords: | Aryloxyphenoxypropionic acid Chiral herbicide Cyanuric chloride Esters R R-Diastereomer |
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