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Melamine-(H_2SO_4)_3 and PVP-(H_2SO_4)_n as solid acids:Synthesis and application in the first mono-and di-nitration of bisphenol A and other phenols
Authors:Gholamabbas Chehardoli  Mohammad Ali Zolfigolb  Seyedeh Bahareh Azimic  Ebadollah Alizadehd a School of Pharmacy  Hamedan University of Medical Sciences  Hamedan   Iran b Faculty of Chemistry  Bu-Ali Sina University  Hamedan  Iran c Islamic Azad University  Shahre Rey Branch  Shahre Rey  Iran d Payame Noor University  Iran
Affiliation:a School of Pharmacy, Hamedan University of Medical Sciences, Hamedan 65178, Iran;b Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran;c Islamic Azad University, Shahre Rey Branch, Shahre Rey, Iran;d Payame Noor University, Hamedan, Iran
Abstract:Melamine and poly vinylpyrrolidone(PVP) reacted with neat sulfuric acid readily to form two new organic solid acids namely melamine-(H_2SO_4)_3 and PVP-(H_2SO_4)_n.These solid acids were used for the first nitration of bisphenol A as well as other phenols in the presence of NH_4NO_3.Mono- and di-nitro bisphenol A have been characterized with IR and ~1H NMR techniques.
Keywords:Bisphenol A  Melamine-(H_2SO_4)_3  Nitration  PVP-(H_2SO_4)_n  Phenols  
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