A new method for the generation of stable phenoxyl radicals by the reaction of [(Me3Si)2N]2E (E = Ge,Sn) with sterically hindered phenols |
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| Authors: | Orlov I S Moiseeva A A Butin E P Egorov M P |
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| Institution: | (1) Russian Academy of Sciences, N. D. Zelinsky Institute of Organic Chemistry, 47 Leninsky prosp., 119991 Moscow, Russian Federation;(2) Department of Chemistry, Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
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| Abstract: | An unusual reaction of diaminogermylene and diaminostannylene with sterically hindered phenols which leads to the formation of stable phenoxyl radicals in high concentrations was found. The reaction mechanism was proposed. Amides (Me3Si)2N]2E (E = Ge, Sn) were investigated electrochemically. |
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| Keywords: | diaminogermylene diaminostannylene sterically hindered phenols deprotonation reaction ESR |
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