Photoproduction of remarkably stable benzylic radicals in cyclodextrin inclusion complexes |
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Authors: | V. Pushkara Rao Matthew B. Zimmt Nicholas J. Turro |
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Affiliation: | Chemistry Department, Columbia University, New York, NY 10027 U.S.A. |
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Abstract: | Photolysis of cyclodextrin inclusion complexes of diastereomers of ,′-dimethyldibenzyl ketone in the solid state resulted in stable benzylic radicals at room temperature. These radicals were characterized by their electron spin resonance (ESR) signals, emission and excitation spectra. |
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