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| 一个生物相关单一手性二维金属有机鲱骨形分子网格:双-3-氨基-(S)-酪氨酸钴(Ⅱ) | |
| 引用本文： | 高小勇,邢立新,陈振锋,包燕雏,杨际虹,吴美芳,熊仁根,游效曾,范洪筠.一个生物相关单一手性二维金属有机鲱骨形分子网格:双-3-氨基-(S)-酪氨酸钴(Ⅱ)[J].无机化学学报,2003,19(8):802-806. |
| 作者姓名： | 高小勇 邢立新 陈振锋 包燕雏 杨际虹 吴美芳 熊仁根 游效曾 范洪筠 |
| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 2. 南京大学分析中心,南京,210093 3. X-Ray Crystallography Unit,School of physics,Universiti Sains Malaysia,11800,USM,Penang,Malaysia |
| 基金项目： | 国家重点基础研究发展计划(973计划) |
| 摘 要： | The first example of homochiral two-dimensional neutral cobalt(Ⅱ)-3-amino-(S)-tyrosine (ATYR) coordination polymer, bis(3-amino-(S)-tyrosinato)cobalt(Ⅱ) 1 was synthesized under the hydrothermal reaction of Co(ClO4)2·6H2O with ATYR in which 1 displays modest second harmonic generation response. |
| 关 键 词： | 3-酪氨基-S-氨酸 二价钴离子 单一手性 配位聚合物 |
| 收稿时间： | 5/5/2003 12:00:00 AM |
| 修稿时间： | 2003/6/20 0:00:00 |
Synthesis and Crystal Structure of a Biologically Relevant Homochiral Two-dimensional Metal-organic Herring-bone Molecular Grid: Bis (3-amino- ( S )-tyrosinato)cobalt (Ⅱ) |
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| GAO Xiao-Yong,XING Li-Xin,CHEN Zhen-Feng,BAO Yan-Chu,YANG Ji-Hong,WU Mei-Fang,XIONG Ren-Gen,YOU Xiao-Zeng and FUN Hoong-Kun.Synthesis and Crystal Structure of a Biologically Relevant Homochiral Two-dimensional Metal-organic Herring-bone Molecular Grid: Bis (3-amino- ( S )-tyrosinato)cobalt (Ⅱ)[J].Chinese Journal of Inorganic Chemistry,2003,19(8):802-806. | |
| Authors: | GAO Xiao-Yong XING Li-Xin CHEN Zhen-Feng BAO Yan-Chu YANG Ji-Hong WU Mei-Fang XIONG Ren-Gen YOU Xiao-Zeng and FUN Hoong-Kun |
| Institution: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;Analylic Center, Nanjing University, Nanjing 210093;Analylic Center, Nanjing University, Nanjing 210093;Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093;X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800, USM, Penang, Malaysia |
| Abstract: | The first example of homochiral two-dimensional neutral cobalt (Ⅱ)-3-amino-( S)-tyrosine (ATYR) coordination polymer,bis(3-amino-(S)-tyrosinato)cobalt(Ⅱ)1 was synthesized under the hydrothermal reaction of Co(ClO4)2·6H2O with ATYR in which 1 displays modest second harmonic generation response. |
| Keywords: | 3-amino-( S )-tyrosine cobalt (Ⅱ) homochiral coordination polymer |
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