4-Nitrophenyl sulfenyl chloride as a new precursor for the formation of aromatic SAMs on gold surfaces |
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| Authors: | Houmam Abdelaziz Muhammad Hamida Chahma M'hamed Koczkur Kallum Thomas Daniel F |
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| Institution: | Electrochemical Technology Centre, Department of Chemistry, University of Guelph, Guelph, Ontario, Canada, N1G 2W1. ahoumam@uoguelph.ca |
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| Abstract: | 4-Nitrophenyl sulfenyl chloride was used as a new precursor for the formation of densely packed aromatic SAMs on gold. The adsorption involves the reductive dissociation of the S-Cl bond. A well-ordered row structure corresponding to a √3 × 4 phase with a molecular area of 27.8 ?(2) is obtained. |
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