| The Performance of Rhodium Complex—diphosphine Systems in the Hydroformylation of 1—Dodecene |
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| 引用本文： | XueYuanHUANG RuiXiangLI HuaCHEN XianJunLI. The Performance of Rhodium Complex—diphosphine Systems in the Hydroformylation of 1—Dodecene[J]. 中国化学快报, 2003, 14(6): 623-626 |
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| 作者姓名： | XueYuanHUANG RuiXiangLI HuaCHEN XianJunLI |
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| 作者单位： | DepartmentofChemistry,SichuanUniversity,Chengdu610064 |
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| 基金项目： | 国家重点基础研究发展计划(973计划) |
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| 摘 要： | The catalytic performances of four HRh(CO)(PPh3)3-diphosphine (BISBI,BDPX,BDNA and BINAP) systems in 1-dodecene hydroformylation were investigated and compared with HRh(CO)(PPh3)3-PPh3 system.The catalyst system HRb(CO)(PPh3)3-BISBI exhibited very hig regioselectivity for the formation of linear aldehyde.
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| 关 键 词： | 铑配合物 二磷烷 羰基化作用 十二碳烯 催化反应 催化剂 |
The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene |
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| Xue Yuan HUANG,Rui Xiang LI,Hua CHEN,Xian Jun LI. The Performance of Rhodium Complex-diphosphine Systems in the Hydroformylation of 1-Dodecene[J]. Chinese Chemical Letters, 2003, 14(6): 623-626 |
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| Authors: | Xue Yuan HUANG Rui Xiang LI Hua CHEN Xian Jun LI |
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| Abstract: | The catalytic performances of four HRh(CO)(PPh3)3-diphosphine (BISBI,BDPX, BDNA and BINAP) systems in 1-dodecene hydroformylation were investigated and compared with HRh(CO)(PPh3)3-PPh3 system. The catalyst system HRh(CO)(PPh3)3-BISBI exhibited very high regioselectivity for the formation of linear aldehyde. |
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| Keywords: | Hydroformylation 1-dodecene diphosphine rhodium complex. |
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