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Metal-free activation of EH3 (E = P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HSi=AsH subunit
Authors:Präsang Carsten  Stoelzel Miriam  Inoue Shigeyoshi  Meltzer Antje  Driess Matthias
Affiliation:Technische Universit?t Berlin, Institute of Chemistry: Metalorganics and Inorganic Materials, Sekretariat C2, Strasse des 17. Juni 135, 10623 Berlin (Germany), Fax: (+49)?30‐314‐29732 http://www.driess.tu‐berlin.de
Abstract:
Keywords:arsanes  density functional calculations  N‐heterocyclic silylenes  phosphanes  zwitterions
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