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青蒿素及其类似物的结构和合成 VIII:^1H核磁共振测定青蒿素降解物及有关化合物的构型
引用本文:陈朝环,周维善.青蒿素及其类似物的结构和合成 VIII:^1H核磁共振测定青蒿素降解物及有关化合物的构型[J].化学学报,1983,41(9):853-856.
作者姓名:陈朝环  周维善
作者单位:中国科学院上海有机化学研究所
摘    要:

关 键 词:测定  核磁共振谱法  化学位移  青蒿素  构型  降解产物  

Studies on structure and synthesis of arteannuin and related compounds VIII: Determination of configuration of arteannuin degradation products and related compounds by ^1H NMR spectroscopy
CHEN CHAOHUAN,ZHOU WEISHAN.Studies on structure and synthesis of arteannuin and related compounds VIII: Determination of configuration of arteannuin degradation products and related compounds by ^1H NMR spectroscopy[J].Acta Chimica Sinica,1983,41(9):853-856.
Authors:CHEN CHAOHUAN  ZHOU WEISHAN
Abstract:The present report deals with the stereochemistry of the degradation products of arteannuin and some intermediates of its total synthesis. The configurations of 13-CH3 and lactone ring are deduced by using spin-spin coupling constants and the pattern of 11-H as well as the NOE results from 1H NMR spectroscopy.
Keywords:DETERMINATION  NMR SPECTROMETRY  CHEMICAL SHIFT  ARTEANNUIN  CONFIGURATION  DEGRADATION PRODUCTS
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