Changes in motion vs. bonding in positively vs. negatively cooperative interactions |
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Authors: | Williams Dudley H Calderone Christopher T O'Brien Dominic P Zerella Rosa |
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Institution: | Cambridge Centre for Molecular Recognition, Dept. of Chemistry, Lensfield Road, Cambridge, UK CB2 1EW. dhwl@cam.ac.uk |
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Abstract: | From a consideration of the interactions between non-covalent bonds, it is concluded that positively cooperative binding will occur with a benefit in enthalpy and a cost in entropy, and that negatively cooperative binding will occur with a cost in enthalpy and a benefit in entropy; experimental data support these conclusions. |
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