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Complex Analysis of Phosphate-based Material Oxidation |
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| Authors: | Yatsimirsky V K Boldyreva N A Lisnyak V V Slobodyanik N S |
| Institution: | (1) Department of Chemistry, Taras Shevchenko Kyiv University, 64 Vladimirskaya Str., 01033 Kyiv, Ukraine;(2) Department of Chemistry, Taras Shevchenko Kyiv University, 64 Vladimirskaya Str., 01033 Kyiv, Ukraine |
| Abstract: | The thermal stability of sample Mo(PO3)3 that is the initial material for novel catalysts for carbonmonoxide oxidation has been studied. It has been concluded that molybdenum(III) methaphosphate is stable up to 435°C. Processes of partial oxidation and layering of specimens are determined. Novel material based on partial oxidized Mo(PO3)3 gives significant rise of the carbon oxidation rate. The molybdenum(III) metaphosphate is of a definite interest in view of its application in practice as initial material for new catalysts row formation with different content of Mo(PO3)3 and MoOPO4 layers. This revised version was published online in August 2006 with corrections to the Cover Date. |
| Keywords: | carbon monoxide oxidation catalyst molybdenum(III) metaphosphate thermal stability |
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