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Dispersion relations for stark energy shifts in hydrogen atom
Authors:S C Kanavi  C H Mehta  S H Patil
Institution:Department of Physics, Indian Institute of Technology, Bombay-400 076, India;Mathematics Group, R and D Division, Institute for Petroleum Exploration, ONGC, Dehradun 248195, India;Department of Physics, Indian Institute of Technology, Bombay-400 076, India
Abstract:On the basis of an approximate but nonperturbative expression for the energy shift δE in the ground state of the hydrogen atom in the presence of an electric field of strength , we deduce that δE has a branch point at = 0, and an asymptotic behavior ln as → ∞. These properties lead to a twice-subtracted dispersion relation for δE as a function of . The dispersion relations in conjunction with the WKB approximation and the perturbation series allow us to (i) deduce the large-n behavior of the coefficient of n in the perturbation series for δE( ) including 1/n corrections and (ii) obtain the energy shift and the level width of the ground state for a large range of values of . The agreement with the earlier numerical calculations is very satisfactory.
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