Structural modification of unsymmetrically substituted monophthalocyanines by nucleophilic reactions |
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Authors: | A. Yu. Tolbin L. G. Tomilova N. S. Zefirov |
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Affiliation: | (1) Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992 Moscow, Russian Federation;(2) Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severnyi proezd, 142432 Chernogolovka, Moscow region, Russian Federation |
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Abstract: | New 2-nitro-substituted phthalocyanine zinc complexes were synthesized. The nucleophilic substitution of the NO2 group was used for the first time for the structural modification of unsymmetrically substituted monophthalocyanines. The electronic absorption spectra of phthalocyanines were studied. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2036–2040, September, 2005. |
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Keywords: | unsymmetrically substituted monophthalocyanines synthesis nucleophilic substitution |
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