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Spectrum of hot water in the 2000-4750 cm frequency range |
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| Authors: | Nikolai F. Zobov,Sergei V. Shirin,Oleg L. Polyansky,Robert J. Barber,Pierre-Franç ois Coheur,Peter F. Bernath,Michel Carleer |
| Affiliation: | a Department of Physics and Astronomy, University College London, London, WC1E 6BT, UK b Arbeitsgruppe Chemieinformationssysteme, Albert-Einstein-Allee 47, Ulm University, Ulm, Germany c Université Libre de Bruxelles, Service de Chimie Quantique et Photophysique, 50 Av. F.D. Roosevelt, B-1050 Bruxelles, Belgium d Department of Chemistry, University of Waterloo, Waterloo, Ont., Canada N2L 3G1 e Department of Chemistry, University of Arizona, Tucson, AZ 85721, USA |
| Abstract: | An emission spectrum recorded in an oxyacetylene torch [P.-F. Coheur, P.F. Bernath, M. Carleer, R. Colin, O.L. Polyansky, N.F. Zobov, S.V. Shirin, R.J. Barber, J. Tennyson, J. Chem. Phys. 122 (2005) 074307] is analyzed for the region covering stretching fundamentals and associated hot bands of water. Many lines could be assigned on the basis of previously determined energy levels. New assignments made with a new variational linelist allow a further 800 energy levels covering 15 vibrational states and rotations up to J = 32 to be assigned. A simultaneous re-analysis of previously reported sunspot absorption spectra leads to the assignment of 581 further lines in the L-band spectrum and 67 in the N-band spectrum. |
| Keywords: | Water vapor Line assignments Sunspots |
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