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New GC quartz-lined aluminum capillary columns coated with graphitized carbon black modified by liquid phases
Authors:F Bruner  M Attaran Rezai  L Lattanzi
Institution:(1) Centro di Studio per la Chimica dell' Ambiente e le Metodologie Strumentali Avanzate, c/o Istituto di Scienze Chimiche, Università, Piazza Rinascimento 6, 61029 Urbino, Italy
Abstract:Summary Fused silica is by far the best material for most kinds of GC capillary columns but in some particular conditions, when a drastic or alkaline treatment is required, this material and especially the polyimide protector layer do not possess high chemical resistance and could easily break down. In order to overcome this disadvantage, in this paper, we present a new type of column — a quartz-lined aluminum capillary coated with graphitized carbon black modified by liquid phases by using a new coating procedure. With the above material a capillary column for amine analysis, and another for the analysis of VOCs and oil products are obtained. Some characteristic applications of both columns are reported.
Keywords:Capillary gas chromatography  Aluminum capillary columns  Amine analysis  Highly chemical resistant capillaries
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