Interaction of 1-chloro-1,3,5,7-tetramethyl-2,4,6,8-tetrathioprotoadamantane with mercapto and amino compounds |
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| Authors: | B M Lerman Z Ya Aref'eva L I Umanskaya G A Tolstikov |
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| Institution: | (1) Departments of Anesthesiology and Pharmacology, University of California, San Diego, Anesthesia Research Lab (MC 0818), 9500 Gilman Drive, La Jolla, California, 92093, USA |
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| Abstract: | | 1. |
The reaction between 1-chloro-1,3,5,7-tetramethyl-2,4,6,8-tetrathioprotoadamantane and mercapto-compounds or weakly basic amines produces sulfides and amine derivatives with the protostructure. When (II) reacts with strongly basic amines, dehydrochloridation takes place.
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The reaction between 9-bromo-1,3,5,7-tetramethyl-2,4,6,8-tetrathioadamantane and thioacetic acid in ethanol in presence of alkali proceeds by regrouping, with the formation of the thiolacetate of 2,4,6,8-tetra-thioprotoadamantane.
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